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Rather than asking people for colour names or colour categories, we ask
observers to select the colour which appears ‘neither red nor green’ (yielding
unique yellow and unique blue) or ‘neither yellow nor blue’ (yielding
unique red and unique green).

The figure above shows an example of a typical
stimulus to asses ‘unique red’. The observer selected that
patch which appeared neither yellow nor blue. Since we obtain these
unique hue settings at different luminance (V) and
saturation levels (S), as shown in the figure below, we have
many points in
3-dimensional (LMS) cone space that correspond to a particular
hue. This will allow us to determine quantitatively how the cone
signals are related to a particular perceived hue.

Hering and Urfarben
The idea of ‘unique hues’ was first mentioned by Ewald H Hering
(1834-1918), who referred to these colours as ‘Urfarben’, see
figure below. Colour-normal human observers have usually no difficulty
in making these hue judgements.
 
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